Diffusion is the
spreading out of particles in a gas or liquid. The net movement of particles
from an area of which they are of high concentration (many in a certain volume)
to an area of low concentration.
Diffusion in gases
experiment:
When ammonia gas (NH3) and hydrogen chloride
(HCl) mix, they react together to form a white solid called ammonium
chloride (NH4Cl). Pieces of cotton wool are soaked in
concentrated ammonia solution (a source of ammonia gas) and concentrated
hydrochloric acid (a source of hydrogen chloride gas). These are placed at the
end of a long glass tube with rubber bungs at the ends, in order to stop the
poisonous gases from escaping.
The ammonia and hydrogen chloride particles diffuse along the tube, and
a white ring of solid ammonium chloride forms where they meet. The white ring
of ammonium chloride takes time to form (because the particles move freely and
collide with air particles), and it appears closer to the hydrogen chloride
side. This is because ammonia particles are lighter than hydrogen chloride
particles and therefore travel faster.
Diffusion in
liquids:
Diffusion in a liquid can be extremely slow through a liquid if the
liquid is still. This is because liquid particles move more slowly than gas
particles, and because there are only small gaps (less space) between the
particles of liquid for the other particles to diffuse into, for example
potassium manganate (VII) in water.
Varying the dilution of the
solution, for example adding more water causes the potassium manganate
particles to spread further apart from one another, making the solution less
purple.
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